2024
MDPI journal, Switzerland: Nanomaterials 2024

Dynamics of Photoinduced Charge Carriers in Metal-Halide Perovskites

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Abstract

The measurement and description of the charge-carrier lifetime (𝜏c) is crucial for the wide-ranging applications of lead-halide perovskites. We present time-resolved microwave-detected photoconductivity decay (TRMCD) measurements and a detailed analysis of the possible recombination mechanisms including trap-assisted, radiative, and Auger recombination. We prove that performing injection-dependent measurement is crucial in identifying the recombination mechanism. We present temperature and injection level dependent measurements in CsPbBr3, which is the most common inorganic lead-halide perovskite. In this material, we observe the dominance of charge-carrier trapping, which results in ultra-long charge-carrier lifetimes. Although charge trapping can limit the effectiveness of materials in photovoltaic applications, it also offers significant advantages for various alternative uses, including delayed and persistent photodetection, charge-trap memory, afterglow light-emitting diodes, quantum information storage, and photocatalytic activity.

Topic

perovskites; photoconductivity; photonic applications; charge-carrier lifetime

Author

Andás Bojtor, Dávid Krisztián, Ferenc Korsós, Sándor Kollarics (3,4), Gábor Paráda, Márton Kollár (5), Endre Horváth (5), Xavier Mettan (5), Bence G. Márkus (6, 3, 4), László Forró (6), Ferenc Simon (6, 7, 1, 3)

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